What is Palladium
Palladium is a chemical element with atomic number 46 which means there are 46 protons and 46 electrons in the atomic structure. The chemical symbol for Palladium is Pd.
Palladium, platinum, rhodium, ruthenium, iridium and osmium form a group of elements referred to as the platinum group metals (PGMs). These have similar chemical properties, but palladium has the lowest melting point and is the least dense of them.
More than half the supply of palladium and its congener platinum is used in catalytic converters.
Palladium – Properties
|Element Category||Transition Metal|
|Phase at STP||Solid|
|Atomic Mass [amu]||106.42|
|Density at STP [g/cm3]||12.023|
|Electron Configuration||[Kr] 4d10|
|Possible Oxidation States||+2,4|
|Electron Affinity [kJ/mol]||53.7|
|Electronegativity [Pauling scale]||2.2|
|1st Ionization Energy [eV]||8.3369|
|Year of Discovery||1803|
|Discoverer||Wollaston, William Hyde|
|Melting Point [Celsius scale]||1554.9|
|Boiling Point [Celsius scale]||2963|
|Thermal Conductivity [W/m K]||72|
|Specific Heat [J/g K]||0.24|
|Heat of Fusion [kJ/mol]||17.6|
|Heat of Vaporization [kJ/mol]||357|
See also: Properties of Palladium
Atomic Mass of Palladium
Atomic mass of Palladium is 106.42 u.
Note that, each element may contain more isotopes, therefore this resulting atomic mass is calculated from naturally-occuring isotopes and their abundance.
The unit of measure for mass is the atomic mass unit (amu). One atomic mass unit is equal to 1.66 x 10-24 grams. One unified atomic mass unit is approximately the mass of one nucleon (either a single proton or neutron) and is numerically equivalent to 1 g/mol.
For 12C the atomic mass is exactly 12u, since the atomic mass unit is defined from it. For other isotopes, the isotopic mass usually differs and is usually within 0.1 u of the mass number. For example, 63Cu (29 protons and 34 neutrons) has a mass number of 63 and an isotopic mass in its nuclear ground state is 62.91367 u.
There are two reasons for the difference between mass number and isotopic mass, known as the mass defect:
- The neutron is slightly heavier than the proton. This increases the mass of nuclei with more neutrons than protons relative to the atomic mass unit scale based on 12C with equal numbers of protons and neutrons.
- The nuclear binding energy varies between nuclei. A nucleus with greater binding energy has a lower total energy, and therefore a lower mass according to Einstein’s mass-energy equivalence relation E = mc2. For 63Cu the atomic mass is less than 63 so this must be the dominant factor.
See also: Mass Number
Density of Palladium
Density is defined as the mass per unit volume. It is an intensive property, which is mathematically defined as mass divided by volume:
ρ = m/V
In words, the density (ρ) of a substance is the total mass (m) of that substance divided by the total volume (V) occupied by that substance. The standard SI unit is kilograms per cubic meter (kg/m3). The Standard English unit is pounds mass per cubic foot (lbm/ft3).
See also: What is Density
See also: Densest Materials of the Earth
Electron Affinity and Electronegativity of Palladium
Electron Affinity of Palladium is 53.7 kJ/mol.
Electronegativity of Palladium is 2.2.
In chemistry and atomic physics, the electron affinity of an atom or molecule is defined as:
the change in energy (in kJ/mole) of a neutral atom or molecule (in the gaseous phase) when an electron is added to the atom to form a negative ion.
X + e– → X– + energy Affinity = – ∆H
In other words, it can be expressed as the neutral atom’s likelihood of gaining an electron. Note that, ionization energies measure the tendency of a neutral atom to resist the loss of electrons. Electron affinities are more difficult to measure than ionization energies.
An atom of Palladium in the gas phase, for example, gives off energy when it gains an electron to form an ion of Palladium.
Pd + e– → Pd– – ∆H = Affinity = 53.7 kJ/mol
To use electron affinities properly, it is essential to keep track of sign. When an electron is added to a neutral atom, energy is released. This affinity is known as the first electron affinity and these energies are negative. By convention, the negative sign shows a release of energy. However, more energy is required to add an electron to a negative ion which overwhelms any the release of energy from the electron attachment process. This affinity is known as the second electron affinity and these energies are positive.
Affinities of Non metals vs. Affinities of Metals
- Metals: Metals like to lose valence electrons to form cations to have a fully stable shell. The electron affinity of metals is lower than that of nonmetals. Mercury most weakly attracts an extra electron.
- Nonmetals: Generally, nonmetals have more positive electron affinity than metals. Nonmetals like to gain electrons to form anions to have a fully stable electron shell. Chlorine most strongly attracts extra electrons. The electron affinities of the noble gases have not been conclusively measured, so they may or may not have slightly negative values.
Electronegativity, symbol χ, is a chemical property that describes the tendency of an atom to attract electrons towards this atom. For this purposes, a dimensionless quantity the Pauling scale, symbol χ, is the most commonly used.
The electronegativity of Palladium is:
χ = 2.2
In general, an atom’s electronegativity is affected by both its atomic number and the distance at which its valence electrons reside from the charged nucleus. The higher the associated electronegativity number, the more an element or compound attracts electrons towards it.
The most electronegative atom, fluorine, is assigned a value of 4.0, and values range down to cesium and francium which are the least electronegative at 0.7.
First Ionization Energy of Palladium
First Ionization Energy of Palladium is 8.3369 eV.
Ionization energy, also called ionization potential, is the energy necessary to remove an electron from the neutral atom.
X + energy → X+ + e−
where X is any atom or molecule capable of being ionized, X+ is that atom or molecule with an electron removed (positive ion), and e− is the removed electron.
A Palladium atom, for example, requires the following ionization energy to remove the outermost electron.
Pd + IE → Pd+ + e− IE = 8.3369 eV
The ionization energy associated with removal of the first electron is most commonly used. The nth ionization energy refers to the amount of energy required to remove an electron from the species with a charge of (n-1).
1st ionization energy
X → X+ + e−
2nd ionization energy
X+ → X2+ + e−
3rd ionization energy
X2+ → X3+ + e−
Ionization Energy for different Elements
There is an ionization energy for each successive electron removed. The electrons that circle the nucleus move in fairly well-defined orbits. Some of these electrons are more tightly bound in the atom than others. For example, only 7.38 eV is required to remove the outermost electron from a lead atom, while 88,000 eV is required to remove the innermost electron. Helps to understand reactivity of elements (especially metals, which lose electrons).
In general, the ionization energy increases moving up a group and moving left to right across a period. Moreover:
- Ionization energy is lowest for the alkali metals which have a single electron outside a closed shell.
- Ionization energy increases across a row on the periodic maximum for the noble gases which have closed shells.
For example, sodium requires only 496 kJ/mol or 5.14 eV/atom to ionize it. On the other hand neon, the noble gas, immediately preceding it in the periodic table, requires 2081 kJ/mol or 21.56 eV/atom.
Palladium – Melting Point and Boiling Point
Melting point of Palladium is 1554.9°C.
Boiling point of Palladium is 2963°C.
Note that, these points are associated with the standard atmospheric pressure.
Boiling Point – Saturation
In thermodynamics, the term saturation defines a condition in which a mixture of vapor and liquid can exist together at a given temperature and pressure. The temperature at which vaporization (boiling) starts to occur for a given pressure is called the saturation temperature or boiling point. The pressure at which vaporization (boiling) starts to occur for a given temperature is called the saturation pressure. When considered as the temperature of the reverse change from vapor to liquid, it is referred to as the condensation point.
Melting Point – Saturation
In thermodynamics, the melting point defines a condition in which the solid and liquid can exist in equilibrium. Adding a heat will convert the solid into a liquid with no temperature change. The melting point of a substance depends on pressure and is usually specified at standard pressure. When considered as the temperature of the reverse change from liquid to solid, it is referred to as the freezing point or crystallization point.
Palladium – Specific Heat, Latent Heat of Fusion, Latent Heat of Vaporization
Specific heat of Palladium is 0.24 J/g K.
Latent Heat of Fusion of Palladium is 17.6 kJ/mol.
Latent Heat of Vaporization of Palladium is 357 kJ/mol.
Specific heat, or specific heat capacity, is a property related to internal energy that is very important in thermodynamics. The intensive properties cv and cp are defined for pure, simple compressible substances as partial derivatives of the internal energy u(T, v) and enthalpy h(T, p), respectively:
where the subscripts v and p denote the variables held fixed during differentiation. The properties cv and cp are referred to as specific heats(or heat capacities) because under certain special conditions they relate the temperature change of a system to the amount of energy added by heat transfer. Their SI units are J/kg K or J/mol K.
Different substances are affected to different magnitudes by the addition of heat. When a given amount of heat is added to different substances, their temperatures increase by different amounts.
Heat capacity is an extensive property of matter, meaning it is proportional to the size of the system. Heat capacity C has the unit of energy per degree or energy per kelvin. When expressing the same phenomenon as an intensive property, the heat capacity is divided by the amount of substance, mass, or volume, thus the quantity is independent of the size or extent of the sample.
Latent Heat of Vaporization
In general, when a material changes phase from solid to liquid, or from liquid to gas a certain amount of energy is involved in this change of phase. In case of liquid to gas phase change, this amount of energy is known as the enthalpy of vaporization, (symbol ∆Hvap; unit: J) also known as the (latent) heat of vaporization or heat of evaporation. As an example, see the figure, which descibes phase transitions of water.
Latent heat is the amount of heat added to or removed from a substance to produce a change in phase. This energy breaks down the intermolecular attractive forces, and also must provide the energy necessary to expand the gas (the pΔV work). When latent heat is added, no temperature change occurs. The enthalpy of vaporization is a function of the pressure at which that transformation takes place.
Latent Heat of Fusion
In case of solid to liquid phase change, the change in enthalpy required to change its state is known as the enthalpy of fusion, (symbol ∆Hfus; unit: J) also known as the (latent) heat of fusion. Latent heat is the amount of heat added to or removed from a substance to produce a change in phase. This energy breaks down the intermolecular attractive forces, and also must provide the energy necessary to expand the system (the pΔV work).
The liquid phase has a higher internal energy than the solid phase. This means energy must be supplied to a solid in order to melt it and energy is released from a liquid when it freezes, because the molecules in the liquid experience weaker intermolecular forces and so have a higher potential energy (a kind of bond-dissociation energy for intermolecular forces).
The temperature at which the phase transition occurs is the melting point.
When latent heat is added, no temperature change occurs. The enthalpy of fusion is a function of the pressure at which that transformation takes place. By convention, the pressure is assumed to be 1 atm (101.325 kPa) unless otherwise specified.
Palladium in Periodic Table