When dealing with Prandtl numbers, we have to define a laminar part of the Prandtl number and a turbulent part of the Prandtl number. The equation Pr = ν/α shows us only the laminar part, which is only valid for laminar flows. The following equation shows us the effective Prandtl number:
Preff = ν/α + νt/αt
where νt is kinematic turbulent viscosity, and αt is turbulent thermal diffusivity. The turbulent Prandtl number (Prt = νt/αt) is a non-dimensional term defined as the ratio between the momentum eddy diffusivity and the heat transfer eddy diffusivity. It simply describes mixing because of the swirling/rotation of fluids. The simplest model for Prt is the Reynolds analogy, which yields a turbulent Prandtl number of 1.
In the special case where the Prandtl number and turbulent Prandtl number both equal unity (as in the Reynolds analogy), the velocity profile and temperature profiles are identical. This greatly simplifies the solution of the heat transfer problem. The turbulent Prandtl number is around 0.7 for different free shear layers from experimental data. For near-wall flows, it is larger (Prt = 0.9) and occasionally beyond 1 since it tends to grow larger when nearing the walls.