The Schmidt number describes the mass momentum transfer, and the equations can be seen below:
- ν is the momentum diffusivity (kinematic viscosity) [m2/s]
- μ is the dynamic viscosity [N.s/m2]
- D is the mass diffusivity [m2/s]
- ρ is the density [kg/m3]
It physically relates the relative thickness of the hydrodynamic layer and mass-transfer boundary layer. The Schmidt number corresponds to the Prandtl number in heat transfer. A Schmidt number of unity indicates that momentum and mass transfer by diffusion are comparable, and velocity and concentration boundary layers almost coincide with each other. Mass diffusivity or diffusion coefficient is a proportionality constant between the molar flux due to molecular diffusion and the gradient in the concentration of the species (or the driving force for diffusion). Mass diffusion in liquids grows with temperature, roughly inversely proportional viscosity-variation with temperature, so that the Schmidt number, Sc=ν/D, quickly decreases with temperature. For example, the diffusion coefficient for ethanol in water is Dethanol,water=1.6⋅10−9 and gives the Schmidt number Sc = 540, which is typical for liquids.
Diffusivity is encountered in Fick’s law, which states:
If the concentration of a solute in one region is greater than in another of a solution, the solute diffuses from the region of higher concentration to the region of lower concentration, with a magnitude that is proportional to the concentration gradient.
In one (spatial) dimension, the law is:
- J is the diffusion flux,
- D is the diffusion coefficient,
- φ (for ideal mixtures) is the concentration.
The use of this law in nuclear reactor theory leads to the diffusion approximation.
Turbulent Schmidt Number
Similarly as for the Prandtl number, also Schmidt number has a special formula for turbulent flow. The turbulent Schmidt number describes the ratio between the rates of turbulent transport of momentum and the turbulent transport of mass. The turbulent Schmidt number is commonly used in turbulence research and is defined as:
Sc = νt/K
- νt is the eddy viscosity [m2/s]
- K is the eddy diffusivity [m2/s]