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Wiedemann–Franz Law – Lorenz Number

At a given temperature, metals’ thermal and electrical conductivities are proportional, but raising the temperature increases the thermal conductivity while decreasing the electrical conductivity. This behavior is quantified in the Wiedemann–Franz law. This law states that the ratio of the electronic contribution of the thermal conductivity (k) to the electrical conductivity (σ) of metal is proportional to the temperature (T).

Wiedemann-Franz Law - Lorentz Number - definition

Qualitatively, this relationship is based upon the fact that heat and electrical transport both involve the free electrons in the metal. The electrical conductivity decreases with particle velocity increases because the collisions divert the electrons from forwarding transport of charge. However, the thermal conductivity increases with the average particle velocity, increasing the forward transport of energy. The Wiedemann-Franz law is generally well obeyed at high temperatures. In the low and intermediate temperature regions, however, the law fails due to the inelastic scattering of the charge carriers.

It must be noted, the general correlation between electrical and thermal conductance does not hold for other materials, due to the increased importance of phonon carriers for heat in non-metals.

 
References:
Heat Transfer:
  1. Fundamentals of Heat and Mass Transfer, 7th Edition. Theodore L. Bergman, Adrienne S. Lavine, Frank P. Incropera. John Wiley & Sons, Incorporated, 2011. ISBN: 9781118137253.
  2. Heat and Mass Transfer. Yunus A. Cengel. McGraw-Hill Education, 2011. ISBN: 9780071077866.
  3. Fundamentals of Heat and Mass Transfer. C. P. Kothandaraman. New Age International, 2006, ISBN: 9788122417722.
  4. U.S. Department of Energy, Thermodynamics, Heat Transfer and Fluid Flow. DOE Fundamentals Handbook, Volume 2 of 3. May 2016.

Nuclear and Reactor Physics:

  1. J. R. Lamarsh, Introduction to Nuclear Reactor Theory, 2nd ed., Addison-Wesley, Reading, MA (1983).
  2. J. R. Lamarsh, A. J. Baratta, Introduction to Nuclear Engineering, 3d ed., Prentice-Hall, 2001, ISBN: 0-201-82498-1.
  3. W. M. Stacey, Nuclear Reactor Physics, John Wiley & Sons, 2001, ISBN: 0- 471-39127-1.
  4. Glasstone, Sesonske. Nuclear Reactor Engineering: Reactor Systems Engineering, Springer; 4th edition, 1994, ISBN: 978-0412985317
  5. W.S.C. Williams. Nuclear and Particle Physics. Clarendon Press; 1 edition, 1991, ISBN: 978-0198520467
  6. G.R.Keepin. Physics of Nuclear Kinetics. Addison-Wesley Pub. Co; 1st edition, 1965
  7. Robert Reed Burn, Introduction to Nuclear Reactor Operation, 1988.
  8. U.S. Department of Energy, Nuclear Physics and Reactor Theory. DOE Fundamentals Handbook, Volume 1 and 2. January 1993.
  9. Paul Reuss, Neutron Physics. EDP Sciences, 2008. ISBN: 978-2759800414.

Advanced Reactor Physics:

  1. K. O. Ott, W. A. Bezella, Introductory Nuclear Reactor Statics, American Nuclear Society, Revised edition (1989), 1989, ISBN: 0-894-48033-2.
  2. K. O. Ott, R. J. Neuhold, Introductory Nuclear Reactor Dynamics, American Nuclear Society, 1985, ISBN: 0-894-48029-4.
  3. D. L. Hetrick, Dynamics of Nuclear Reactors, American Nuclear Society, 1993, ISBN: 0-894-48453-2. 
  4. E. E. Lewis, W. F. Miller, Computational Methods of Neutron Transport, American Nuclear Society, 1993, ISBN: 0-894-48452-4.

See above:

Thermal Conductivity