In general, semiconductors are materials, inorganic or organic, which have the ability to control their conduction depending on chemical structure, temperature, illumination, and presence of dopants. The name semiconductor comes from the fact that these materials have an electrical conductivity between that of a metal, like copper, gold, etc. and an insulator, such as glass. They have an energy gap less than 4eV (about 1eV). In solid-state physics, this energy gap or band gap is an energy range between valence band and conduction band where electron states are forbidden. In contrast to conductors, electrons in a semiconductor must obtain energy (e.g., from ionizing radiation) to cross the band gap and to reach the conduction band. Properties of semiconductors are determined by the energy gap between valence and conduction bands.
Silicon as Semiconductor
Silicon is a chemical element with atomic number 14 which means there are 14 protons and 14 electrons in the atomic structure. The chemical symbol for Silicon is Si. Silicon is a hard and brittle crystalline solid with a blue-grey metallic lustre, it is a tetravalent metalloid and semiconductor. Silicon is mainly used for charged particle detectors (especially for tracking charged particles) and soft X-ray detectors. The large band-gap energy (Egap= 1.12 eV) allows us to operate the detector at room temperature, but cooling is prefered to reduce noise. Silicon based detectors are very important in high-energy physics. Since silicon-based detectors are very good for tracking charged particles, they constitute a substantial part of detection system at the LHC in CERN.
Silicon-based Semiconductor Detectors
Silicon-based semiconductor detectors are mainly used for charged particle detectors (especially for tracking charged particles) and soft X-ray detectors while germanium is widely used for gamma ray spectroscopy. A large, clean and almost perfect semiconductor is ideal as a counter for radioactivity. However, it is difficult to make large crystals with sufficient purity. The semiconductor detectors have, therefore, low efficiency, but they do give a very precise measure of the energy. Detectors based on silicon have sufficiently low noise even by room temperature. This is caused by the large band gap of silicon (Egap= 1.12 eV), which allows us to operate the detector at room temperature, but cooling is prefered to reduce noise. The drawback is that silicon detectors are much more expensive than cloud chambers or wire chambers and require sophisticated cooling to reduce leakage currents (noise). They also suffer degradation over time from radiation, however this can be greatly reduced thanks to the Lazarus effect.
See also: Germanium Detectors, MIRION Technologies. <available from: https://www.mirion.com/products/germanium-detectors>.