At temperatures near a gases boiling point, increases in pressure will cause condensation to take place and drastic decreases in volume. At very high pressures, the intermolecular forces of a gas are significant. However, most gases are in approximate agreement at pressures and temperatures above their boiling point. The ideal gas law is utilized by engineers working with gases because it is simple to use and approximates real gas behavior.
See also: Elastic Collision
Equation of State
Any equation that relates the pressure, temperature, and specific volume of a substance is called an equation of state. The simplest and best-known equation of state for substances in the gas phase is the Ideal Gas equation of state.
pV = nRT
- p is the absolute pressure of the gas
- n is the amount of substance
- T is the absolute temperature
- V is the volume
- R is the ideal, or universal, gas constant, equal to the product of the Boltzmann constant and the Avogadro constant,
In this equation the symbol R is a constant called the universal gas constant that has the same value for all gases—namely, R = 8.31 J/mol K.