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Plutonium 239

Plutonium 239, 239Pu, is a fissile isotope, which means 239Pu can undergo a fission reaction after absorbing a thermal neutron. Moreover, 239Pu also meets the alternative requirement that the amount (~2.88 per one fission by thermal neutron) of neutrons produced by fission of 239Pu is sufficient to sustain a nuclear fission chain reaction. This isotope is the principal fissile isotope of plutonium in use. It is a manufactured isotope and can be found in irradiated uranium fuel or spent uranium fuel. Isotope 239Pu is formed in a nuclear reactor from fertile isotope 238U, constituting more than 95% of uranium fuel (e.g.,, PWRs and BWRs require 3% – 5% of 235U). Absorption of resonance or thermal neutron by the 238U nucleus yields 239U. The half-life of 239U is approximately 23.5 minutes. 239U decays (negative beta decay) to 239Np (neptunium), whose half-life is 2.36 days. 239Np decays (negative beta decay)  to 239Pu. The transmutation and decay chain is shown below:Equation - Plutonium 239 breeding from Uranium 238239Pu itself decays via alpha decay into 235U with a half-life of 24 100 years. 239Pu occasionally decays by spontaneous fission with a very low rate of 0.00000000031%. On the other hand, 239Pu has a very high absorption cross-section for thermal neutrons. When loaded into the reactor core, 239Pu can be easily fissioned by a neutron or transformed into the 240Pu via a radiative capture reaction.

Plutonium 239 Fission

Plutonium 239 is a fissile isotope, and its fission cross-section for thermal neutrons is about 750 barns (for 0.025 eV neutron). For fast neutrons, its fission cross-section is on the order of barns. Most absorption reactions result in fission reaction, but a part of reactions result in radiative capture forming 240Pu. The cross-section for radiative capture for thermal neutrons is about 270 barns (for 0.025 eV neutron). Therefore about 27% of all absorption reactions result in radiative capture of incident neutron. About 73% of all absorption reactions result in fission.

Plutonium fission vs. radiative capture

Typically, when the plutonium 239 nucleus undergoes fission, the nucleus splits into two smaller nuclei (triple fission can also rarely occur) and a few neutrons (the average is 2.89 neutrons per fission by thermal neutron) and release of energy in the form of heat and gamma rays. The average of the fragment atomic mass is about 120, but very few fragments near that average are found. It is much more probable to break up into unequal fragments, and the most probable fragment masses are around mass numbers 103 and 134 (and around atomic numbers 40 – Zirconium and 54 – Xenon).

Most of these fission fragments are highly unstable (radioactive) and undergo further radioactive decays to stabilize themselves. Therefore part of the released energy is radiated away from the reactor. On the other hand, most of the energy released by one fission (~175MeV of total ~207MeV) appears as kinetic energy of these fission fragments. The fission fragments interact strongly with the surrounding atoms or molecules traveling at high speed, causing them to ionize. The creation of ion pairs requires energy, which is lost from the kinetic energy of the charged fission fragment, causing it to decelerate. The positive ions and free electrons created by the passage of the charged fission fragment will then reunite, releasing energy in the form of heat (e.g.,, vibrational energy or rotational energy of atoms). This is the principle of how fission fragments heat fuel in the reactor core.

plutonium breedingSource of data: JANIS (Java-based Nuclear Data Information Software); The JEFF-3.1.1 Nuclear Data Library
Fissile / Fertile Material Cross-sectionsFissile / Fertile Material Cross-sections. Comparison of total fission cross-sections.Source: JANIS (Java-based Nuclear Data Information Software); ENDF/B-VII.1
Fissile / Fertile Material Cross-sectionsPlutonium 239. Comparison of total fission cross-section and cross-section for radiative capture.

Source: JANIS (Java-based Nuclear Data Information Software); ENDF/B-VII.1

Neutron production per one fission of Plutonium 239.Neutron production per one fission of Plutonium 239.
Source: JANIS (Java-based Nuclear Data Information Software)
The JEFF-3.1.1 Nuclear Data Library
Fission fragment yieldsFission fragment yield for different nuclei. The most probable fragment masses for 239Pu fission are around mass 103 (Zirconium) and 134 (Xenon).

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Half-life of Plutonium

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Plutonium 240